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Effect of CO in activating gas on the pore structure of activated carbon fiber with CO_2 activation

机译:活化气体中CO对CO_2活化对活性炭纤维孔结构的影响

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摘要

Compared with traditional porous carbon materials, activated carbon fibers (ACFs) have unique characteristics, such as fast intraparticle adsorption kinetics, leading to increasing application in gas phase and aqueous phase adsorption [1]. Porosity in ACF depends on the method of preparation and precursor material [2]. Activated carbons prepared from CO-2 activation exhibit a larger micropore volume and a narrower micropore size distribution that those prepared from water steam activation [3,4]. The product gases, CO and H_2 exhibit product inhibition in the C-CO_2 and C-H_2O reaction [4]. In addition, the type of porosity created by gasification is also affected by the product gases CO and H_2 [5].
机译:与传统的多孔碳材料相比,活性碳纤维(ACF)具有独特的特性,例如快速的颗粒内吸附动力学,从而导致在气相和水相吸附中的应用不断增加[1]。 ACF中的孔隙度取决于制备方法和前体材料[2]。由CO-2活化制备的活性炭与由水蒸汽活化制备的活性炭相比,具有更大的微孔体积和更窄的微孔尺寸分布[3,4]。产物气,CO和H_2在C-CO_2和C-H_2O反应中表现出产物抑制作用[4]。另外,由气化产生的孔隙类型也受到产物气体CO和H_2的影响[5]。

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