TOUGHNESS AND MICROSCOPIC FRACTURE MECHANISMS OF UNFILLED AND SHORT-GLASS-FIBRE-FILLED POLY(CYANO ARYLETHER)

摘要

Fracture mechanisms of an advanced high-strength thermoplastic poly(cyano arylether) (PCAE) and its short-glass-fibre (SGF)-reinforced composites have been studied in relation to toughnesses K-C and J(C). Test temperatures were 23 and 100 degrees C. Reflected and transmitted optical observations were combined with scanning electron microscopy for the fractographic investigation. For unreinforced PCAE tested at 100 degrees C, the damage area in front of a notch becomes fairly large in size and consists of numerous tensile microfailures around the local plastic yielding zone, as compared with that tested at 23 degrees C. This resulted in a substantial improvement of K-C and a big increase in J(C). Filling fibres, however, produced both toughening and anti-toughening results: effects of fibre spanning, pull-out and bridging across the local plastic failure zone and zigzag propagation of fracture due to fibre filling, improved the toughness. However, adhesive failure at the fibre-matrix interface, tensile microcleavage at the fibre ends and straightforward fracture in the skin layer, considerably diminished the values of K-C and J(C), except for the trend of K-C at 23 degrees C. [References: 23]