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Fabrication of polyvinylchloride based nanocomposite thin film filled with zinc oxide nanoparticles: Morphological, thermal and optical characteristics

机译:填充氧化锌纳米粒子的聚氯乙烯基纳米复合薄膜的制备:形貌,热学和光学特性

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摘要

PVC-co-ZnO nanocomposite film was prepared by solution casting technique with different concentration of zinc oxide nanoparticle. Optical measurements showed that utilizing zinc oxide nanoparticle in polymeric matrix caused to increase of UV absorption obviously. X-ray diffraction showed polycrystalline structure with no preferred orientation for prepared nanocomposite films. Atomic force microscopy images also showed smooth surfaces for the nanocomposite films. The thermal properties investigation of prepared films revealed that utilizing ZnO nanoparticles in polymeric matrix accelerated the polymer decomposition which was assigned to catalytic behavior of zinc oxide nanoparticles. Moreover, utilizing zinc oxide nanoparticles enhanced the char yield of prepared films. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
机译:采用溶液流延技术制备了不同浓度氧化锌纳米粒子的PVC-co-ZnO纳米复合薄膜。光学测量表明,在聚合物基质中使用氧化锌纳米颗粒明显增加了紫外线吸收。 X射线衍射显示对于制备的纳米复合膜没有优选取向的多晶结构。原子力显微镜图像还显示出纳米复合膜的光滑表面。制备的膜的热性能研究表明,在聚合物基质中使用ZnO纳米颗粒可加速聚合物分解,这归因于氧化锌纳米颗粒的催化行为。此外,利用氧化锌纳米颗粒提高了制备膜的焦炭收率。 (C)2015韩国工业和工程化学学会。由Elsevier B.V.发布。保留所有权利。

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