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首页> 外文期刊>Journal of industrial and engineering chemistry >Syngas production via dry reforming of methane over Ni/Al2O3-MgO nanocatalyst synthesized using ultrasound energy
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Syngas production via dry reforming of methane over Ni/Al2O3-MgO nanocatalyst synthesized using ultrasound energy

机译:通过超声能量合成的Ni / Al2O3-MgO纳米催化剂上甲烷的干重整制甲烷生产合成气

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摘要

The Ni/Al2O3-MgO nanocatalyst with Al/Mg ratio of 1.5 was prepared successfully using sonochemistry method and shown high activity and stability in dry reforming of methane. XRD, BET, FESEM, TEM and EDAX-dot mapping techniques have been used for nanocatalyst characterization. XRD analysis confirmed the formation of MgO and NiO cubic phases. According to the FESEM micrographs, nanostructure grains with uniform surface size distribution have been observed in of the synthesized nanocatalyst. The TEM micrographs showed that ultrasound-assisted preparation method induced uniform morphology without agglomeration of particles. The activity of synthesized nanocatalyst could reach thermodynamic equilibrium conversions and H2/CO ratios.
机译:采用声化学方法成功制备了Al / Mg比为1.5的Ni / Al2O3-MgO纳米催化剂,并在甲烷干重整中表现出较高的活性和稳定性。 XRD,BET,FESEM,TEM和EDAX点映射技术已用于纳米催化剂的表征。 XRD分析证实了MgO和NiO立方相的形成。根据FESEM显微照片,在合成的纳米催化剂中观察到具有均匀表面尺寸分布的纳米结构晶粒。 TEM显微照片显示,超声辅助制备方法可诱导均匀的形貌,而不会发生颗粒团聚。合成的纳米催化剂的活性可以达到热力学平衡转化率和H2 / CO比。

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