Study of collisional deactivation of O_2(b ~1Σ _g ~+) molecules in a hydrogen-oxygen mixture at high temperatures using laser-induced gratings

摘要

Collisional deactivation of O_2(b~1Σ _g ~+) molecules resonantly excited by a 10 ns pulse of laser radiation with a wavelength of 762 nm in H_2/O_2 mixtures is experimentally studied. The radiation intensity and hence the molecule excitation efficiency have a spatially periodic modulation that leads to the formation of laser-induced gratings (LIGs) of the refractive index. The study of LIG temporal evolution allows collisional relaxation rates of molecular excited states and gas temperature to be determined. In this work, the b ~1Σ _g ~+ state of O_2 molecules deactivation rates are measured in a 4.3 vol % H_2 mixture at the number density of 2 amg in the temperature range 291-850 K. The physical deactivation is shown to dominate in the collisions of H2 with O _2(b ~1Σ _g ~+) and O _2(a ~1Δ _g) up to temperatures of 780-790 K at time delays up to 10 μs after the excitation pulse. The parameters of the obtained temperature dependence of the (b ~1Σ _g ~+ state deactivation rate agree well with the data of independent measurements performed earlier at lower temperatures (200-400 K). Tunable diode laser absorption spectroscopy is used to measure the temperature dependence of the number density of the H_2O molecules which appear as the mixture, as the result of the dark gross reaction with O_2 molecules in the ground state, O_2 + 2H_2 → 2H_2O. The measurements show that this reaction results in complete transformation of H_2 into H_2O at temperatures of 790-810 K.