An electrochemical sensor based on the three-dimensional functionalized graphene for simultaneous determination of hydroquinone and catechol

摘要

In this study, a simple and sensitive electrochemical analytical method is developed for simultaneous detection of hydroquinone (HQ) and catechol (CC) employing the three-dimensional functionalized graphene (3DFG) modified glass carbon electrode (GCE). The 3DFG modified electrode can distinguish between HQ and CC, with higher oxidation currents in comparison with bare GCE and two-dimensional graphene (Gr) modified electrode, showing the enhanced catalytic activity. The differential pulse voltammetry (DPV) shows that the isomers can be detected sensitively and selectively at 3DFG/GCE with peak-to-peak separation about 100 mV. Under the optimized conditions, the oxidation peak current increases linearly with concentration of HQ ranged from 3.10 × 10~(-7) to 1.31 × 10~(-5) M and concentration of CC ranged from 2.50 × 10~(-7) to 1.29 × 10~(-5) M, respectively. The detection limits are 1.0 × 10~(-7) Mand 8.0 × 10~(-8) Mfor HQ and CC (S/N = 3), respectively. Moreover, the proposed method has been successfully applied to the simultaneous determination of HQ and CC in real water samples with satisfactory recoveries.