AMIDOBENZOATE AND CARBOXYLATE BONDING OF 2-AMINO-3-METHYLBENZOIC ACID IN AN OXORHENIUM(V) COMPLEX

T.I.A. GERBER; D. LUZIPO; P. MAYER

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AMIDOBENZOATE AND CARBOXYLATE BONDING OF 2-AMINO-3-METHYLBENZOIC ACID IN AN OXORHENIUM(V) COMPLEX

机译：氧化HEN（V）络合物中2-氨基-3-甲基苯甲酸的氨基苯甲酸根和羧酸根键合

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The complex [ReO(Hamb)(H_2amb)(PPh_3)] (1) was prepared by the reaction of m-[ReO_2l(PPh_3)_2] with two equivalents of 2-amino-3-methylbenzoic acid (H_3amb) in toluene under reflux conditions. Crystallographic data show that 1 contains the coordinated amidobenzoate chelate (Hamb) and symmetrically chelating carboxylate ion (H_2amb) in a pseudo-octahedral geometry.

机译：配合物[ReO（Hamb）（H_2amb）（PPh_3）]（1）是通过m- [ReO_2l（PPh_3）_2]与两当量的2-氨基-3-甲基苯甲酸（H_3amb）在甲苯中的反应制备的回流条件。晶体学数据显示1以伪八面体几何形状包含配位的酰氨基苯甲酸酯螯合物（Hamb）和对称的螯合羧酸根离子（H_2amb）。

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来源
《Journal of Coordination Chemistry》 |2004年第16期|共5页
作者
T.I.A. GERBER; D. LUZIPO; P. MAYER;
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正文语种 eng
中图分类无机化学;
关键词
Rhenium; Amidobenzoate; Carboxylate; Anthranilic acid derivative;

机译：hen;氨基苯甲酸酯;羧酸盐;邻氨基苯甲酸衍生物;

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1. AMIDOBENZOATE AND CARBOXYLATE BONDING OF 2-AMINO-3-METHYLBENZOIC ACID IN AN OXORHENIUM(V) COMPLEX [J] . T.I.A. GERBER, D. LUZIPO, P. MAYER Journal of Coordination Chemistry . 2004,第16期

机译：氧化HEN（V）络合物中2-氨基-3-甲基苯甲酸的氨基苯甲酸根和羧酸根键合
2. Substituent effects in hydrogen bonding: DFTand QTAIMstudies on acids and carboxylates complexes with formamide [J] . Borys O?mia?owski Journal of molecular modeling . 2014,第8期

机译：氢键中的取代基作用：DFT和QTAIM研究酸和羧酸盐与甲酰胺的配合物
3. Hydrogen Bonds in the 1:1 and 2:1 Complexes of 1-Methylquinolinium-3-carboxylate with Mineral Acids Studied by NMR, FTIR and Raman Spectra and DFT Calculations [J] . P. Barczynski, M. Szafran Polish Journal of Chemistry . 2009,第5期

机译：NMR，FTIR和拉曼光谱及DFT计算研究1-甲基喹啉-3-羧酸与羧酸的1：1和2：1配合物中的氢键
4. Molecular recognition:stereoselective complexation of small peptides and amino acid carboxylates in aqueous solutions.Automated,parallel synthesis of a guanidinocarbonyl pyrrole receptor library [C] . U.Hackler Interantional Meeting on Chemical Engineering and Biotechnology . 2001

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5. Mechanistic Studies of New Bond Forming Reactions Mediated by Oxorhenium(V) and Cp*Iridium Complexes [D] . Robbins, Leanna Kate 2016

机译：Ox（V）和Cp *铱配合物介导的新键形成反应的机理研究
6. Substituent effects in hydrogen bonding: DFT and QTAIM studies on acids and carboxylates complexes with formamide [O] . Borys Ośmiałowski -1

机译：氢键中的取代基效应：DFT和QTAIM研究甲酰胺与酸和羧酸盐的配合物
7. Substituent effects in hydrogen bonding: DFT and QTAIM studies on acids and carboxylates complexes with formamide [O] . Borys Ośmiałowski 2014

机译：氢键中的取代基效应：DFT和QTAIM研究甲酰胺与酸和羧酸盐的配合物
8. Studies of hydrogen-hydrogen and carbon-sulfur bond cleavage; Lewis acid modified molybdenum sulfide complexes; and Syntheses and reactions of pyrrole complexes. Final report [R] . 1998

机译：研究氢 - 氢和碳 - 硫键裂解;路易斯酸改性硫化钼配合物;和吡咯配合物的合成和反应。总结报告

AMIDOBENZOATE AND CARBOXYLATE BONDING OF 2-AMINO-3-METHYLBENZOIC ACID IN AN OXORHENIUM(V) COMPLEX

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