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Comparative analysis on the microstructure and property of Ni-based coatings remelted by laser and flame

机译:激光和火焰重熔镍基涂层的组织和性能比较分析

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摘要

Ni60 coatings have been prepared by flame spraying and flame remelting process and by flame spraying and laser remelting process on the surface of low-carbon steel (Q235) respectively. The developed Ni60 coatings were characterized by using scanning electronic microscope (SEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and micro-hardness tester. Corrosion resistance of the coatings was measured using corrosion weight loss method. The results show that the microstructure of laser remelted coatin gs contains fine grains and a large number of dendrites. However, the microstructure of flame remelted coatings contains coarse massive grains. In both flame remelted and laser remelted coatings the white-bright dendrites consist of γ-(FeNi) solid solution, and grey matrix between dendrites consist of the eutectic of γ-(FeNi) and Cr _7C _3, CrB, Ni 3B. In addition, grey matrix between dendrites for flame remelted coatings contains the oxide phases, such as Cr _2O _3, NiCr _2O _4, Fe _2O _3. The even hardness of flame remelted coatings is higher than that of laser remelted coatings, but its hardness distribution is non-uniform. And corrosion resistance in sulfuric acid solution of laser remelted Ni60 coatings is superior to that of flame remelted coatings.
机译:通过火焰喷涂和火焰重熔工艺以及火焰喷涂和激光重熔工艺分别在低碳钢(Q235)表面制备了Ni60涂层。通过使用扫描电子显微镜(SEM),X射线衍射(XRD),能量色散光谱(EDS)和显微硬度测试仪对Ni60涂层进行了表征。使用腐蚀失重法测量涂层的耐腐蚀性。结果表明,激光重熔涂层的微观结构含有细晶粒和大量枝晶。但是,火焰重熔涂层的微观结构含有粗大的块状晶粒。在火焰重熔涂层和激光重熔涂层中,白色明亮的树枝状晶体由γ-(FeNi)固溶体组成,树枝状晶体之间的灰矩阵由γ-(FeNi)和Cr_7C_3,CrB,Ni 3B的共晶组成。另外,用于火焰重熔涂层的枝晶之间的灰矩阵包含氧化物相,例如Cr _2O _3,NiCr _2O _4,Fe _2O _3。火焰重熔涂层的平均硬度高于激光重熔涂层,但其硬度分布不均匀。 Ni60激光重熔涂层在硫酸溶液中的耐蚀性优于火焰重熔涂层。

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