Visible-light-driven hydrogen production with extremely high quantum efficiency on Pt-PdS/CdS photocatalyst

摘要

To efficiently convert solar energy into chemical energy by artificial photosynthesis, we need to develop visible-light-responsive photocatalysts with a high quantum efficiency (QE). Here we report that an artificial photocatalyst (Pt-PdS/CdS) can achieve a QE up to 93% in photocatalytic H_2 production in the presence of sacrificial reagents under visible light irradiation, and is very stable under the photocatalytic reaction conditions. The extremely high QE could be achieved by loading as low as 0.30 wt% of Pt and 0.13 wt% of PdS as cocatalysts on CdS.