Synthesis and characterization of epoxy-modified cement slurries-Kinetic data at hardened slurries/HCl interfaces

摘要

In this study, two new epoxy-modified oilwell cement slurries were synthesized. All characterization measurements were performed and compared in relation to a standard cement slurry, which was synthesized using only cement and water. The XRD patterns, as well as TG/DTG and DSC analyses have suggested that portlandite (Ca(OH)(2)) and carbonate phases were not present in detectable amounts in the new cement slurries. The isothermal kinetic data of the interaction of HCl with the epoxymodified cement were obtained using the batch mode from 25 to 55 degrees C. The kinetic data were best fitted to the second-order and the Avrami kinetic models, since differences between experimental and calculated values were lower for these models. The intraparticle diffusion model has pointed out that the new slurries present positive values for the parameter "C," which is related to higher boundary layer resistance to HCl diffusion into the internal parts of the slurries, in relation to the standard slurry. The characterization and the HCI interaction kinetic studies have suggested that the new cement slurries present good potential, from the chemical viewpoint, to be used in oilwell operations. (C) 2008 Elsevier Inc. All rights reserved.