首页> 外文期刊>Journal of Chemical and Engineering Data: the ACS Journal for Data >Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K
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Excess Molar Volumes and Speed of Sound in Bromotrichloromethane + n-Heptane, Dibromomethane + n-Heptane, Bromotrichloromethane + Dibromomethane, and Bromotrichloromethane + Bromochloromethane at Temperatures from (293.15 to 313.15) K

机译:在(293.15至313.15)K的温度下,溴三氯甲烷+正庚烷,二溴甲烷+正庚烷,溴三氯甲烷+二溴甲烷和溴三氯甲烷+溴氯甲烷中的过量摩尔体积和声速

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摘要

Density and speed of sound of four binary mixtures bromotrichloromethane + n-heptane, dibromomethane + n-heptane, bromotrichloromethane + dibromomethane, and bromotrichloromethane + bromochloromethane were measured over the entire range of composition in the temperature range from T = 293.15 K to T = 313.15 K. Excess molar volumes and deviation in isentropic compressibility have been calculated from experimental measurements and fitted to a Redlich-Kister equation to derive binary coefficients and the standard deviation.
机译:在T = 293.15 K至T = 313.15的整个温度范围内,测量了溴三氯甲烷+正庚烷,二溴甲烷+正庚烷,溴三氯甲烷+二溴甲烷和溴三氯甲烷+溴氯甲烷这四种二元混合物的密度和声速。 K.从实验测量中计算出了过量的摩尔体积和等熵可压缩性偏差,并将其拟合到Redlich-Kister方程中,以得出二元系数和标准偏差。

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