Adsorption and Selective Separation of Neodymium with Magnetic Alginate Microcapsules Containing the Extractant 2-Ethylhexyl Phosphonic Acid Mono-2-ethylhexyl Ester

摘要

Magnetic alginate microcapsules containing the extractant 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (PS07) were prepared for adsorption and selective separation of neodymium using equilibrium batch experiments. The effect of various parameters such as adsorbent dose, contact time, temperature, pH, and metal ion concentration on adsorption was investigated. The results demonstrated that the adsorption data fit well the pseudosecond order kinetic model, and the Langmuir adsorption isotherm was suitable for the description of adsorption process. The adsorption capacity had the order Pb~(2+) > Nd~~(3+) > Cu~(2+) > Zn~(2+) > Co~(2+) > Ni~(2+) for mono- and multicomponent systems, and Nd~(3+) could be selectively separated from the mixed Nd~(3+)/Co~(2+) and Nd~(3+)/Zn~(2+) solutions over the whole concentration range. Furthermore, solvent extraction and ion exchange mechanisms were confirmed to contribute to the adsorption process by FTIRspectra studies, pH analyses, and adsorption isotherms with possible structures of the complex proposed. Thermogravimetric analysis, desorption, and regeneration tests forecasted that the magnetic alginate P507 microcapsules would be an excellent candidate for their potential industrial application.