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Influence of Wood Welding Frequency on Wood Constituents Chemical Modifications

机译:木材焊接频率对木材成分化学改性的影响

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摘要

Interesting chemical differences betwen weldlines obtained at 100 Hz and 150 Hz frequencies in linear vibration wood welding were observed by FT-IR and ~(13)C NMR. An increase in the proportion of unoxidized phenolic groups in the lignin is observed by FT-IR and the increased joint strength observed is ascribed to the improved adhesion derived from this. The much decreased level of oxidation due to the much shorter welding time possible at 150 Hz was clearly observed by ~(13)C NMR by a marked decrease,even disappearance,of the presence of dark coloured quinones in the weldline at 150 Hz. This yielded colourless weldlines.
机译:通过FT-IR和〜(13)C NMR观察到在线性振动木焊接中以100 Hz和150 Hz频率获得的焊缝之间有趣的化学差异。通过FT-IR观察到木质素中未氧化的酚基的比例增加,并且观察到的增加的结合强度归因于由此产生的改善的粘附性。通过〜(13)C NMR可以清楚地看到由于在150 Hz时可能要短得多的焊接时间而导致的氧化程度大大降低,而在150 Hz时焊缝中深色醌的存在显着减少甚至消失。这产生了无色的焊缝。

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