Viscoelastic and adhesion properties of EVA/tackifier/wax ternary blend systems as hot-melt adhesives

摘要

Two types of wax were added to a ethylene vinyl acetate (EVA)copolymer/aromatic hydrocarbon resin (tackifier)blend in the molten state and the miscibility,viscoelastic and adhesion properties of ternary blends as hot-melt adhesives (HMAs)were investigated.Miscibility and viscoelastic properties were studied using differential scanning calorimetry (DSC),Brookfield vis-cometry and dynamic mechanical thermal analysis (DMTA),and their adhesion strength was determined in terms of single lap shear strength.DSC thermograms of both types of waxes showed their melting peaks in a similar region to that of EVA/tackfier blend.It was difficult to evaluate the miscibility of ternary blends using DSC because the melting peaks of the waxes overlapped with those of the EVA/tackifier blend,although the glass transition temperature (T_g)of the ternary blend systems slightly increased with increasing wax concentration.However,their storage modulus (E')increased slightly and loss tangent (tan delta)showed different peaks when two types of wax were added to the EVA/tackifier blend.Therefore,the miscibility of EVA/tackifier blend altered with addition of waxes.In addition,their melt viscosity decreased with increasing wax concentration.Furthermore,the adhesion strength of the ternary blends decreased with increasing wax concentration,despite the increment of storage modulus.These results suggested that the ternary blends of EVA/tackifier/wax were heterogeneous.