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Transglutaminase treatment of wool fabrics leads to resistance to detergent damage

机译:羊毛织物的转谷氨酰胺酶处理可抵抗洗涤剂的破坏

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摘要

Biological detergents are now routinely used in domestic laundry because the enzymes they contain provide the added benefit of low temperature washes with improved cleaning performance. One of the key enzymes found in these detergents are proteases, which if exposed to natural protein fibres such as wool or silk can cause irreversible damage, leading to loss of fabric strength, shape and poor colour fastness. Transglutaminases (TGases) are protein cross-linking enzymes capable of adding tensile strength to wool proteins, and as a consequence are capable of remediating the damage caused by previous chemical treatments, and more importantly, by proteases. In this paper we treated dyed wool fabric with TGase and then washed the fabric with biological and non-biological detergents to investigate whether TGases would protect wool garments from damage by the undue use of biological detergents in domestic laundry. We demonstrate using different cycles of detergent washes containing biological and non-biological detergents and different TGase treatments, that wool fabric treated previously with TGase release less dye into the washing liquor and in addition maintain fabric strength at levels greater than the washed controls. As a consequence, wool garments previously treated with TGase are likely to have increased resistance to domestic washing and thus provide increased longevity.
机译:现在,生物洗涤剂通常用于家庭洗衣中,因为它们所含的酶具有低温洗涤的额外好处,并具有改善的清洁性能。这些洗涤剂中发现的关键酶之一是蛋白酶,如果暴露于天然蛋白质纤维(例如羊毛或丝绸)中,会导致不可逆转的损害,从而导致织物强度,形状和色牢度下降。转谷氨酰胺酶(TGases)是一种蛋白质交联酶,能够增加羊毛蛋白的抗张强度,因此能够弥补先前化学处理(更重要的是蛋白酶)引起的破坏。在本文中,我们用TGase处理了染色的羊毛织物,然后用生物和非生物洗涤剂洗涤了织物,以研究TGase是否可以保护羊毛服装不受家庭洗衣中过度使用生物洗涤剂的损害。我们证明了使用不同周期的含有生物和非生物洗涤剂的洗涤剂洗涤以及不同的TGase处理,先前用TGase处理过的羊毛织物向洗涤液中释放的染料更少,此外还能使织物强度保持在高于洗涤的对照水平。结果,先前用TGase处理过的羊毛服装可能具有增加的对家庭洗涤的抵抗力,因此提供了更长的寿命。

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