Polymerization of Methacrylamide in the Presence of Ultrasound and Peroxomonosulphate

摘要

Polymerization of methacrylamide has been carried out in the presence of ultrasound and peroxomonosulphate for the first time. The rate of polymerizaiton and the rate of disappearance of peroxomonosulphate were followed simultaneously. A first order dependence on monomer and half order dependence with respect to peroxomonosulphate were found towards rate of polymerization. However, a first-order dependence on peroxomonosulphate was noted with rate of peroxomonosulpate disappearance. A suitalbe reaction scheme is suggested to fit with the experimental results. The composite rate constants for the polymerization were evaluated and compared for acrylamide and methacrylamide polymerization in the presence of ultrasound.