Uron and Uron-Urea-Formaldehyde Resins

摘要

The favored pH ranges for the formation of urons in urea-formaldehyde (UF) resins preparation were determined, these being at pH's higher than 6 and lower than 4 at which the equilibrium urons reversible N. N'-dimethylol ureas are shifted in favor of the cyclic uron species. Shifting the pH slowly during the preparation from one favorable range of the other causes shift in the equilibrium and formation of a majority of methylol ureas species, whereas a rapid changes in pH does not cause this to any great extent. UF resins in which uron constituted as much as 60% of the resin were prepared and the procedure to maxumize the proportion of uron present at the end of the reaction is described. Uron was found to be present in these resins also as linked by methylene bridges to urea and other urons and also as methylol urons, the reactivity of the methylol groups of this latter having been shown to be much lower than that of the same group in methylol ureas .Thermomechanical analysis (TMA) tests and tests on wood particleboard prepared with uron resins to which relatively small proportions of urea were added at the end of the reaction were capable of gelling and yielding bonds of considerable strength. Equally, mixing a uron-rich resin with a low F/U molar ratio UF resin yielded resins of greater strength than a simiple UF of corresponding molar ratio indicating that UF resins of lower formaldehyde emission with acceptable strength could be prepared with these resins.