Synthesis, characterization, and studies on the solid-state crosslinking of functionalized vinyl cinnamate polymers

摘要

Functionalized vinyl cinnamate monomers were synthesized by the reaction between hydroxyethylacrylate (HEA) and substituted cinnamoyl chlorides possessing electron releasing and withdrawing functional groups like chloro, methoxy, and nitro groups at the para position of the aromatic ring. The structures of these monomers were characterized by Fourier transform infrared (FTIR), H-1-, and C-13-NMR spectral techniques. The homopolymers of the synthesized monomers were obtained by the free radical solution polymerization in dimethylformamide (DMF) at 80 degrees C for 12 h using azobisisobutyronitrile (AIBN) as a radical initiator. The sensitivity of these polymers towards light was studied by monitoring the photocrosslinking nature of the polymers by ultraviolet (UV) and FTIR techniques. The effect of the functional groups on the crosslinking efficiency was studied and compared with that of the unsubstituted polymer. The cyclobutane-type addition mechanism involved in the photocrosslinking phenomena was confirmed by the above spectral studies in the functionalized vinyl cinnamate polymers. (C) 1998 John Wiley & Sons, Inc. [References: 18]