Absorption of Metal Cations by Modified B. mori Silk and Preparation of Fabrics with Antimicrobial Activity

摘要

Silk fabrics were modified by treatment with tannic acid (TA) solution or by acylation with ethylenediaminetetraacetic (EDTA) dianhydride. Kinetics of modification with TA and acylation with EDTA-dianhydride was investigated. The physico-mechanical properties of silk fabrics acylated with EDTA-dianhydride remained un-changed regardless of chemical modification. The absorption of metal cations (Ag~+, Cu~(2+) by untreated and modified silk fabrics was studied as function of the kind of modifying agent, weight gain, and pH of the metal solution. The absorption of Cu~(2+) at alkaline pH was not significantly influenced by chemical modification of the silk substrate. The absorption of Ag~+ by acylated silk remained at a level as low as untreated silk, while was enhanced by TA. The higher the content of TA, the higher the absorption of Ag~+. With respect to the pH of the metal solution, the acylation with EDTA-dianhydride enabled silk to absorb and bind metal cations even in the acidic and neutral pH range, where tannic acid had no effect. Medium to high levels of metal desorption were exhibited by untreated and modified silk fabrics towards the metal cations, with the only exception of the silk-tannic acid-Ag complex, which displayed an extraordinary stability. All metal-containing silks exhibited significant antibacterial activity.