Synthesis of aromatic ring fused pyrrolederivatives by palladium-catalyzed annulation of o-Iodoaryl-amines with allyl acetate

Chang Sung hong; Jae Yong Seo; Eul Kgun Yum; Nack-Do Sung

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Synthesis of aromatic ring fused pyrrolederivatives by palladium-catalyzed annulation of o-Iodoaryl-amines with allyl acetate

机译：钯催化邻碘碘芳基胺与乙酸烯丙酯环化反应合成芳环稠合吡咯烷衍生物

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Indoles,azainodles,and pyrroloquinolines were obtained by palladium-catalyzedannulation of omicron-iodoarylamines with allyl acetate under 5 mol % Pd(OAC)_2,1 equiv.LiCl,3 equiv.K_2CO_3,and 2 qiv.allyl acetate in DMFat 120 degC.pi-Allylpalladium complexes are some of the most widely used synthetic intrmediates in organic synthesis.

机译：通过在5 mol％Pd（OAC）_2,1当量LiCl，3当量K_2CO_3和2乙酸烯丙酯在120°C的DMF中钯与乙酸烯丙酯催化钯-微环化的碘代芳基胺的聚合反应，得到吲哚，氮杂吲哚和吡咯并喹啉。 π-烯丙基钯配合物是有机合成中使用最广泛的一些合成中间体。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2004年第3期|共9页
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Chang Sung hong; Jae Yong Seo; Eul Kgun Yum; Nack-Do Sung;
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1. Synthesis of aromatic ring fused pyrrolederivatives by palladium-catalyzed annulation of o-Iodoaryl-amines with allyl acetate [J] . Chang Sung hong, Jae Yong Seo, Eul Kgun Yum, Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2004,第3期

机译：钯催化邻碘碘芳基胺与乙酸烯丙酯环化反应合成芳环稠合吡咯烷衍生物
2. Synthesis of Multiply Substituted Polycyclic Aromatic Hydrocarbons by Iridium-Catalyzed Annulation of Ring-Fused Benzocyclobutenol with Alkyne through C-C Bond Cleavage [J] . Yu Jiajia, Yan Hong, Zhu Chen Angewandte Chemie . 2016,第3期

机译：通过C-C键切割用炔烃与炔烃环稠合苯并苯并丁烯醇催化环romation催化包扣的倍增多环芳烃
3. Palladium-Catalyzed Tandem Reaction of Yne-Propargylic Carbonates with Boronic Acids:A Simple Method for the Synthesis of Fused Aromatic Rings through Allene-Mediated Electrocyclization [J] . Feng Wang, Xiaofeng Tong, Zhaoguo Zhang Chemistry: A European journal . 2004,第21期

机译：钯催化的炔丙基碳酸酯与硼酸的串联反应：一种通过丙二烯介导的电环化合成熔融芳环的简单方法
4. Palladium-Catalyzed 3+2 Oxidative Annulation of Aromatic Amideswith Maleimides [C] . Qiyuan He, Naoto Chatani 日本化学会春季年会 . 2020

机译：钯催化的芳族酰胺的氧化剂环金属酰胺 - 马来酰亚胺
5. Synthesis of fused ring heterocycles from aromatic and heteroaromatic amines with hydroximoyl chlorides. [D] . Rashid, S. M. Khaledur. 1984

机译：由芳族和杂芳族胺与羟肟基氯合成稠环杂环。
6. Highly Efficient Route to Fused Polycyclic Aromatics via Palladium-Catalyzed Aryne Annulation by Aryl Halides [O] . Zhijian Liu, Richard C. Larock -1

机译：芳烃卤化物通过钯催化的芳烃环化反应获得多环芳烃的高效途径
7. Synthesis of Fused Polycyclic Aromatics by Palladium-Catalyzed Annulation of Arynes Using 2-Halobiaryls [O] . -1

机译：用2-卤圆环酮钯催化芳香族催化的多环芳烃的合成

Synthesis of aromatic ring fused pyrrolederivatives by palladium-catalyzed annulation of o-Iodoaryl-amines with allyl acetate

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