FACILE SYNTHESIS OF GLYCIDATES VIA OXIDATION OF ACRYLATES WITH AQUEOUS SOLUTION OF NaOCl IN THE PRESENCE OF AMMONIUM SALTS

摘要

Various glycidates were obtained in high yields via green oxidation of acrylates with aqueous solution of NaOCl in the presence of ammonium salts. The appropriate choice of ammonium salts fitting to the polarity of the substrates and the reaction under slightly basic conditions were essential for efficient reactions.