L-PROLINE-CATALYZED ASYMMETRIC ALDOL CONDENSATION OF TV-SUBSTITUTED ISATINS WITH ACETONE

Gang Chen; Ye Wang; Hongping He

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L-PROLINE-CATALYZED ASYMMETRIC ALDOL CONDENSATION OF TV-SUBSTITUTED ISATINS WITH ACETONE

机译：电视取代的异丁烯与丙酮的L-脯氨酸催化不对称醛缩合

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L-proline-catalyzed asymmetric aldol condensation of several isatin derivatives with acetone is reported.The desired products were obtained in highly yield with the ee among 30-79%.The substitutes of N can deeply effect the ee value of products,and a novel mechanism is also described.

机译：报道了L-脯氨酸催化的几种靛红衍生物与丙酮的不对称羟醛缩合反应。所制得的目标产物收率高，ee在30-79％之间。N的替代物可对产物的ee值产生深远的影响。还描述了机制。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2006年第11期|共7页
作者
Gang Chen; Ye Wang; Hongping He;
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正文语种 eng
中图分类杂环化合物;
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1. L-PROLINE-CATALYZED ASYMMETRIC ALDOL CONDENSATION OF TV-SUBSTITUTED ISATINS WITH ACETONE [J] . Gang Chen, Ye Wang, Hongping He Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2006,第11期

机译：电视取代的异丁烯与丙酮的L-脯氨酸催化不对称醛缩合
2. Influence of a remote sulfinyl group on L-proline-catalyzed direct asymmetric aldol addition of acetone [J] . Villano Rosaria, Acocella Maria Rosaria, Scettri Arrigo Tetrahedron . 2016,第35期

机译：远端亚磺酰基对L-脯氨酸催化的丙酮直接不对称羟醛加成的影响
3. L-Proline-Catalyzed Asymmetric Direct Aldol Reaction of Heteroaromatic Aldehydes and Acetone: Improvement of Catalytic Efficiency in Ionic Liquid bmim [BF4] [J] . K. Rajender Reddy, L. Chakrapani, T. Ramani Synthetic Communications . 2007,第22a24期

机译：L-脯氨酸催化杂芳族醛与丙酮的不对称直接羟醛反应：提高离子液体bmim [BF4]的催化效率
4. Synthesis of Pseudoionones by Aldol Condensation of Citral with Acetone on Li-Modified MgO Catalysts [C] . Veronica K. Dfez, Juana I. Di Cosimo, Carlos R. Apesteguia Organic Reactions Catalysis Society Conference . 2007

机译：用丙酮对锂改性MgO催化剂的副植物凝结副酮的合成
5. Strained silacycles in organic synthesis: The tandem aldol-allylatio/aldol-aldol reaction and their asymmetric variations. [D] . Wang, Xiaolun. 2005

机译：有机合成中的应变硅杂环化合物：串联的羟醛-烯丙基比/羟醛-羟醛反应及其不对称变化。
6. Physico-Chemical Properties of MgGa Mixed Oxides and Reconstructed Layered Double Hydroxides and Their Performance in Aldol Condensation of Furfural and Acetone [O] . Oleg Kikhtyanin, Libor Čapek, Zdeněk Tišler, 2018

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7. l-Proline-Catalyzed Direct Intermolecular Asymmetric Aldol Reactions of 1-Phenylthiocycloalkyl Carboxaldehydes with Ketones. Easy Access to Spiro- and Fused-Cyclobutyl Tetrahydrofurans and Cyclopentanones [O] . -1

机译：L-脯氨酸催化的直接分子间不对称醛醇反应1-苯基硫代环烷基羧醛与酮。轻松进入螺旋和熔融环丁基四氢呋喃和环戊酮

L-PROLINE-CATALYZED ASYMMETRIC ALDOL CONDENSATION OF TV-SUBSTITUTED ISATINS WITH ACETONE

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