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High-temperature-functionalization of surfaces: drag reduction and self-cleaning

机译:表面的高温功能化:减阻和自清洁

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摘要

Increasing requirements on technical components for high-temperature-applications (e.g., turbine blades) demand for new developments in surface engineering. The selective combination of materials with positive and negative thermal expansion coefficients (NTE) will lead to a reversible activation of the surface depending on surface temperature: The generation of a riblet structure ("shark skin") in operation condition by thermal expansion of the matrix and shrinkage of the NTE-ceramic and self-cleaning of the surface at cool down as a result of the reversal of the process. Due to its hygroscopicity the chosen NTE-ceramic Y{sub}2W{sub}3O{sub}12 needs to be embedded into a binder matrix. Therefore a feedstock powder consisting of MCrAlY, WO{sub}3 and Y{sub}2O{sub}3 is mechanically alloyed in a high-energy ball mill. The powder is deposited on substrates by thermal spraying (VPS and HVOF) and laser cladding as well. After coating process a lateral- and depth-selective ion implantation of tungsten, yttrium and oxygen will force nucleation in predefined areas. A following heat treatment of the specimens supports the in-situ-formation of Y{sub}2W{sub}3O{sub}12.
机译:对高温应用的技术组件(例如涡轮叶片)的要求不断提高,这需要对表面工程领域进行新的开发。具有正负热膨胀系数(NTE)的材料的选择性组合将导致表面的可逆活化,具体取决于表面温度:在工作条件下,通过基体的热膨胀产生肋状结构(“鲨鱼皮”)由于该过程的逆转,NTE陶瓷的收缩和冷却时表面的自清洁。由于其吸湿性,需要将所选的NTE陶瓷Y {sub} 2W {sub} 3O {sub} 12嵌入粘合剂矩阵中。因此,由MCrAlY,WO {sub} 3和Y {sub} 2O {sub} 3组成的原料粉末在高能球磨机中机械合金化。粉末通过热喷涂(VPS和HVOF)和激光熔覆沉积在基材上。在涂覆过程之后,钨,钇和氧的横向和深度选择性离子注入将在预定区域内促使形核。样品的后续热处理支持Y {sub} 2W {sub} 3O {sub} 12的原位形成。

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