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Microstructures and oxidation behavior of Cr39Ni7C cermet coatings oeposited by diamond jet spray process

机译:金刚石喷射喷涂Cr39Ni7C金属陶瓷涂层的组织与氧化行为

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摘要

For the promising erosion and oxidation resistance of carbide cermet coating, Cr39Ni7C cermet coatings were deposited by Diamond Jet spray process using a commercial Sulzer Metco 5241 powder in this study. The microstructure, phase composition and high temperature oxidation behavior of the deposited coatings were investigated. The speed and temperature of in-flight particles were measured by DPV-2000. The results revealed that the speed of in-flight particles decreased from 229 m/s to 150 m/s with the increasing of spraying distance from 100 mm to 300 mm, whereas the average temperature of in-flight particles increased from 1926 to 2245 K. The decarburization of Cr{sub}3C{sub}2 increased with the increasing of fuel gas flow from 30 FMR to 40 FMR for higher heat enthalpy of flame. Due to the formation of Cr{sub}2O{sub}3 on/in the coatings at high temperature, the sprayed coatings had good oxidation resistance at 1073 K in air atmosphere. For the lower porosity of the coating deposited under the spraying distance of 150 mm, its oxidation resistance was better than that sprayed under the spraying distance of 200 mm.
机译:为了使碳化物金属陶瓷涂层具有良好的耐蚀性和抗氧化性,本研究中采用商业化的Sulzer Metco 5241粉末通过Diamond Jet喷涂工艺沉积了Cr39Ni7C金属陶瓷涂层。研究了沉积涂层的微观结构,相组成和高温氧化行为。飞行中颗粒的速度和温度通过DPV-2000测量。结果表明,随着喷涂距离从100 mm增加到300 mm,飞行中粒子的速度从229 m / s降低到150 m / s,而飞行中粒子的平均温度从1926年提高到2245 K Cr {sub} 3C {sub} 2的脱碳随着燃料气体流量从30 FMR增加到40 FMR而增加,从而提高了火焰的热焓。由于在高温下在涂层上/之中形成了Cr {sub} 2O {sub} 3,因此喷涂的涂层在空气气氛中在1073 K时具有良好的抗氧化性。对于在150 mm喷涂距离下沉积的涂层较低的孔隙率,其抗氧化性优于在200 mm喷涂距离下喷涂的抗氧化性。

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