Studies on the effect of concentration of formaldehyde on the synthesis of resole-type epoxidized phenolic resin from renewable resource material

摘要

Epoxidized cardanol/formaldehyde resins (ERCF) were synthesized by reacting resole type cardanol/formaldehyde resin and epichlorohydrin in basic medium at 120 °C. Resole-type phenolic resins were synthesized by reacting cardanol and formaldehyde (molar ratios 1:1.3, 1:1.5, 1:1.7, 1:1.9,and 1:2.1) in the presence of sodium hydroxide, as catalyst, at ?ve different temperatures ranging between 60 and 80 °C with an interval of 5°C for a maximum period of 6 h. A set of sam- ples were characterized by Fourier transform infrared and nuclear magnetic resonance spectroscopic analysis. The molec- ular size distribution of resole phenolics was studied by high-resolution gel permeation chromatography. Differential scanning calorimetry technique was used to investigate the curing behavior of the synthesized epoxy resins. Single-step mass loss in dynamic thermo gravimetric traces for the ERCF was observed.