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Effect of Self-Sustained Oscillations on Critical Fluctuations

机译:自持振荡对临界波动的影响

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As is known [1,2], the space of the parameters of an exothermic flow reactor includes a bistability region, where either a low- or high-temperature stationary regime is realized, depending on the initial conditions. The boundary of this region has a cusp, where the difference between regimes disappears. The properties of the cusp are similar to those of a critical point on the phase diagram of a substance with the first-order phase transition between the phases with the same symmetry [3]. In particular, it is the endpoint of the equilibrium line between a liquid and vapor (boiling curve) on the pressure-temperature plane, where the bistability domain is bounded by a spinodal. Fluctuations of the reaction rate must be large near the cusp [4] the same as density fluctuations increase near the critical point. At the same time, this similarity is not universal: the stationary regimes of a reactor lose stability for certain parameter values and become periodic [5-7]. In [4], an increase in fluctuations was calculated in the linear approximation and disregarding the oscillation mode. In this work, critical fluctuations are analyzed by numerical simulation for the conditions when they cannot be treated as small, as well as upon the transition from the stationary regime to the periodic one at the cusp.
机译:众所周知[1,2],放热流反应器的参数空间包括一个双稳态区域,根据初始条件,该区域可实现低温或高温固定状态。该区域的边界处于尖峰,政权之间的差异消失了。尖端的特性类似于具有相同对称性的各相之间具有一阶相变的物质的相图上的临界点[3]。特别是,它是压力-温度平面上液体和蒸汽之间的平衡线的终点(沸腾曲线),其中双稳态域由旋节线界定。在尖端附近,反应速率的波动必须大[4],与在临界点附近密度波动的增加相同。同时,这种相似性不是普遍的:反应堆的静止状态对于某些参数值失去稳定性,并变成周期性的[5-7]。在[4]中,在线性近似中计算了波动增加,而忽略了振荡模式。在这项工作中,通过数值模拟对临界波动进行了分析,以分析无法将其视为很小的情况,以及在稳态时从固定状态过渡到周期性状态的情况。

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