The Synthesis of Substituted 4,4'-Thiobis(Aminophenylglyoxime)and Their Polymeric Metal Complexes with Cu(II),Ni(II)and Co(II)Salts

摘要

4,4'-Bis(chloroacetyl)diphenyl thioether(HL)was synthesized from chloroacetyl chloride and diphenyl thiocther in the presence of A1C1_3 as catalyst in a Friedel-Crafts reaction.Subsequently,its keto oxime(H_2L)and glyoxime(H4L)derivatives were also prepared.Then 3 new substituted 4,4'-thiobis(aminophen-ylglyoxime)(E_4L~(1-3))were synthesized from 4,4'-thiobis(chlorophenylglyoxime)and the corresponding amines.The Ni(II),Cu(II)and Co(II)complexes of these ligands were prepared.The structures of these ligands and their complexes were identifed by FT-IR,~1H NMR and ICP-AES spectral data,elemental analyses and magnetic measurements.