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On the use of linearized pseudo-second-order kinetic equations for modeling adsorption systems

机译:关于使用线性拟二阶动力学方程建模吸附系统

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摘要

Simulated pseudo-second-order kinetic adsorption data were analyzed by different methods of least-squares regression. The methods used were non-linear regression and four linearized forms of the pseudo-second-order equation. The simulated data were compromised with three different homoskedastic and heteroskedastic error distributions. In the presence of all types of error distributions, non-linear regression was the most robust method and provided the most accurate and efficient estimates of the kinetic parameters.
机译:模拟的伪二级动力学吸附数据通过最小二乘回归的不同方法进行了分析。使用的方法是非线性回归和伪二阶方程的四种线性化形式。模拟数据受到三种不同的同方差和异方差误差分布的影响。在存在所有类型的误差分布的情况下,非线性回归是最可靠的方法,并且提供了动力学参数的最准确和最有效的估计。

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