Effect of the substituents on the spin coupling between iminosemiquinone pi-radicals mediated by diamagnetic metal ions: l.s. Co(III) vs Ga(III)

Chaudhuri P; Wagner R; Pieper U; Biswas B; Weyherm T

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Effect of the substituents on the spin coupling between iminosemiquinone pi-radicals mediated by diamagnetic metal ions: l.s. Co(III) vs Ga(III)

机译：取代基对抗磁性金属离子介导的亚氨基半醌π自由基之间自旋偶联的影响： Co（III）与Ga（III）

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Exchange coupling between the radical iminosemiquinone ligands changes from ferromagnetic to antiferromagnetic in l. s. Co(III) complexes 1-5, whereas the same coupling in Ga(III) complexes 6-8 is always antiferromagnetic.

机译：自由基亚氨基半醌配体之间的交换偶联在I中从铁磁性变为反铁磁性。 s。 Co（III）配合物1-5，而Ga（III）配合物6-8中的相同耦合始终是反铁磁性的。

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《Dalton transactions: An international journal of inorganic chemistry 》 |2008年第10期| 共3页
作者
Chaudhuri P; Wagner R; Pieper U; Biswas B; Weyherm T;
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正文语种 eng
中图分类化学 ;
关键词
O-IMINOBENZOSEMIQUINONATO COMPLEXES; ELECTRONIC-STRUCTURE; GROUND-STATE; TRANSITION; OXIDATION; SUPEREXCHANGE; GALLIUM(III); REACTIVITY; DINUCLEAR; ALCOHOLS;

机译：邻-亚氨基苯并半杂芳基化合物;电子结构;基态;转变;氧化;超交换;镓（III）;反应性;核素;醇;

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1. Effect of the substituents on the spin coupling between iminosemiquinone pi-radicals mediated by diamagnetic metal ions: l.s. Co(III) vs Ga(III) [J] . Chaudhuri P, Wagner R, Pieper U, Dalton transactions: An international journal of inorganic chemistry . 2008 ,第10期

机译：取代基对抗磁性金属离子介导的亚氨基半醌π自由基之间自旋偶联的影响： Co（III）与Ga（III）
2. sigma-Bonded organometallic derivatives of yttrium(III) and thulium(III): An unusual ligand coupling reaction mediated by thulium(III) [J] . Bowman LJ, Izod K, Clegg W, Journal of Organometallic Chemistry . 2007 ,第26期

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Effect of the substituents on the spin coupling between iminosemiquinone pi-radicals mediated by diamagnetic metal ions: l.s. Co(III) vs Ga(III)

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