[M-III(bpym)(CN)(4)](-): a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym=2,2 '-bypyrimidine)

Visinescu D; Toma LM; Lloret F; Fabelo O; Ruiz-Perez C; Julve M

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >[M-III(bpym)(CN)(4)](-): a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym=2,2 '-bypyrimidine)

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[M-III(bpym)(CN)(4)](-): a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym=2,2 '-bypyrimidine)

机译：[M-III（bpym）（CN）（4）]（-）：设计亚铁磁性氰基桥联杂双金属链的合适构件（M = Fe，Cr; bpym = 2,2'-嘧啶）

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Two cyano-bridged (MMnIII)-Mn-III [M = Fe (1) and Cr (2)] ferrimagnetic chains are reported; 2 exhibits metamagnetism with two critical fields of 1250 G and 2.0 T which correspond to the overcoming by the applied dc field of the inter- and intrachain magnetic interactions, respectively.

机译：据报道，有两个氰基桥联（MMnIII）-Mn-III [M = Fe（1）和Cr（2）]亚铁磁链。图2展示了具有1250 G和2.0 T的两个临界场的超磁性，这两个临界场分别对应于链间和链内磁相互作用的外加dc场的克服。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2008年第31期|共3页
作者
Visinescu D; Toma LM; Lloret F; Fabelo O; Ruiz-Perez C; Julve M;
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正文语种 eng
中图分类无机化学;
关键词
SINGLE-MOLECULE MAGNET; SCHIFF-BASE; COMPLEXES; ANISOTROPY; TRINUCLEAR; CLUSTERS; CO; MANGANESE(III); PRECURSOR; NI;

机译：单分子磁体;席夫夫基;络合物;各向异性;三核;团簇;CO;锰（III）;PRECURSOR;NI;

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1. [M-III(bpym)(CN)(4)](-): a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym=2,2 '-bypyrimidine) [J] . Visinescu D, Toma LM, Lloret F, Dalton transactions: An international journal of inorganic chemistry . 2008,第31期

机译：[M-III（bpym）（CN）（4）]（-）：设计亚铁磁性氰基桥联杂双金属链的合适构件（M = Fe，Cr; bpym = 2,2'-嘧啶）
2. [Mn_2~(II)(bpym)(H_2O)_8]~(4+) and [Mn~(IV)(CN)_8]~(4-) (M = Mo and W) as building blocks in designing bpym- and cyanide-bridged bimetallic three-dimensional networks (bpym = 2,2'-bipyrimidine) [J] . Juan Manuel Herrera, Donatella Armentano, Giovanni de Munno, New Journal of Chemistry . 2003,第1期

机译：[Mn_2〜（II）（bpym）（H_2O）_8]〜（4+）和[Mn〜（IV）（CN）_8]〜（4-）（M = Mo和W）作为设计bpym-和氰化物桥联的双金属三维网络（bpym = 2,2'-联嘧啶）
3. Synthesis, structure, and magnetic properties of Co-2{[N(CN)(2)](4)bpym}center dot H2O and M{[N(CN)(2)](2)bpym}center dot H2O (M = Mn, Fe, Co; bpym = 2,2 '-bipyrimidine) [J] . Marshall SR., Manson JL., Rheingold AL., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000,第9期

机译：Co-2 {[N（CN）（2）]（4）bpym}中心点H2O和M {[N（CN）（2）]（2）bpym}中心点H2O的合成，结构和磁性能（ M = Mn，Fe，Co; bpym = 2,2'-联嘧啶）
4. First Observation of Photoinduced Magnetization for the Cyano-Bridged 3d-4f Heterobimetallic Assembly Nd(DMF)_4(H_2O)_3(μ-CN)Fe(CN)_5·H_2O (DMF = N,N-Dimethylformamide) [C] . GUANGMING LI, TAKASHIRO AKITSU, OSAMU SATO, International Conference on the Applications of the Mossbauer Effect . 2004

机译：首先观察光纤桥接3D-4F异质组装Nd（DMF）_4（H_2O）_3（μ-CN）Fe（CN）_5·H_2O（DMF = N，N-二甲基甲酰胺）的光致磁化
5. Design of discrete supramolecular architectures via self-assembly of macromolecular building blocks. [D] . Schlueter, Douglas Charles. 1997

机译：通过大分子构件的自组装设计离散的超分子体系结构。
6. Design and synthesis of a bis-macrocyclic host and guests as building blocks for small molecular knots [O] . Elizabeth A Margolis, Rebecca J Keyes, Stephen D Lockey IV, 2020

机译：设计和合成BIS-MACROCYCLIC主机和客人作为小分子结的构建块
7. Fe(bpb)(CN)2- as a Versatile Building Block for the Design of Novel Low-Dimensional Heterobimetallic Systems: Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged FeIII-NiII Complexes (bpb)2- = 1, 2-Bis(pyridine-2-carboxamido)benzenate [O] . -1

机译：Fe（BPB）（CN）2 - 作为新型低维杂化空间系统设计的多功能构建块：氰基桥接FeIII-NiII复合物的合成，晶体结构和磁性性能（BPB）2- = 1,2-双（吡啶-2-羧酰胺）苯甲酸酯
8. nido-Carborane Building-Blocks Reagents. 3. Cyclic and Open-Chain Oligomers Incorporating -CB4H6C- Units. 'Crown' Carboranes [R] . Boyter, H. A., Grimes, R. N. 1988

机译：nido-Carborane Building-Blocks试剂。 3.包含-CB4H6C-单元的环状和开链低聚物。 '皇冠'Carboranes

[M-III(bpym)(CN)(4)](-): a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym=2,2 '-bypyrimidine)

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