A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes on artificial peptides in solution

摘要

A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes has been performed in organic media using, for instance, a synthetic peptide bearing two bis(ethylenediamine)-based Pt(IV) complexes with two axial bromide anionic ligands, [1a(Pt(IV)Br-2(en))(2)](RSO3)(4), and a [Pt(II)(en)(2)](RSO3)(2) complex (R = (C12H25OCH2)(2)CHO(CH2)(3)-).