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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Dynamic behaviour of Ru and Ru-Pt complexes containing tetrahedro-P _4 ligand
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Dynamic behaviour of Ru and Ru-Pt complexes containing tetrahedro-P _4 ligand

机译:含四面体P _4配体的Ru和Ru-Pt配合物的动力学行为

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摘要

Dynamic processes involving the P_4 cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)_2(H)(η~1-P_4)]BF_4 and for the bimetallic derivative trans-[Ru(dppm)_2(H)(μ, η~(1:2)-P_4){Pt(PPh_3)_2}]BF _4 as demonstrated by NMR experiments and DFT calculations.
机译:对于单核络合物反式[[Ru(dppm)_2](H)(η〜1-P_4)] BF_4和双金属衍生物反式[[Ru(dppm)_2] (H)(μ,η〜(1:2)-P_4){Pt(PPh_3)_2}] BF _4由NMR实验和DFT计算证实。

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