A higher yielding route for T_8 silsesquioxane cages and X-ray crystal structures of some novel spherosilicates

摘要

The synthesis of T_8 silsesquioxane cages from trialkoxysilanes using tetra n-butylammonium fluoride is described. The yields are in the range 20-95%, which is a great improvement on other literature routes. This methodology enables a wide range of functionalised T_8 cages to be prepared. The X-ray crystal structures of three new T_8 cages, octacyclopentylsilsesquioxane, and octa(4-carboxymethyl-3,3-dimethylburtyl)-silsesquioxane are also reported.