Self-assembly of star-shaped heteropoly-15-palladate(II)

摘要

A novel heteropolyoxopalladate structural type has beendiscovered: the polyoxo-15-palladate(II) [Pd_(0.4)Na_(0.6) Pd_(15)-P_(10)O_(50)H_(6.6)]~(12--)(Pd_(15))has been prepared in a one-pot self-assembly reaction and characterized by single-crystal XRD,elemental analysis, IR, TGA, ~(31)PNMRand electrochemistry;preliminary catalytic studies showed that Pd_(15)is active as acatalyst in alcohol oxidation by dioxygen.