Synthesis, Structure and Properties of a 2D Cadmium(II) Coordination Polymer Based on Fluconazole and Isophthalate Ligands

摘要

A Cd(II) complex based on fluconazole and isophthalate ligands, {[Cd(HFlu)(IPA)(H_2O)]?H_2O}_n (1), (HFlu=fluconazole; H_2IPA=isophthalic acid) has been synthesized. Single-crystal X-ray analysis reveals that complex 1 has a 2D network structure including unusual triple hydrogen bonds between hydroxyl and triazolyl groups. The complex has also been characterized by IR, UV/Vis and fluorescence spectroscopy, elemental analysis, and thermogravimetry.