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The adhesive and durability of adhesive-poly (ethylene terephthalate) film joints

机译:粘合剂-聚对苯二甲酸乙二醇酯薄膜接头的粘合性和耐久性

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Purpose - The purpose of this paper is to research the durability of the adhesive-poly(ethylene terephthalate) film joints. Design/methodology/approach - The adhesive-poly(ethylene terephthalate) joints are prepared with poly ethylene terephthalate film synthesised from thioglycolic acid, terpene hydrocarbon resin and acetone resolution at room temperature. These joints are characterised by methods of peel strength tests, energy dispersive X-ray spectroscopy (EDX) and analysis of glass transition temperature (Tg) to examine their durability.Findings - Peel strength tests and EDX analyses prove that water diffusion in different humidity aging conditions causes similar changes, namely having the time-temperature equivalence at 45°C for 200,300, 500 and 600 h, respectively, almost corresponding with those at 55℃ for 100,200, 300 and 400 h, respectively, and at 65°C for 50,100,150 and 200 h, respectively. The changes in EDX spectra of adhesive-poly(ethylene terephthalate) film joints indicate that the rate of water penetration in the adhesive is faster than that in the polyethylene terephthalate) film. In humidity aging process, the decline ratio of peel strength of adhesive-poly(ethylene terephthalate) film joints treated with Co~(60) irradiation is lower than that treated with acetone washing or chemical treatment.Originality/value - The paper shows that using EDX for analysis of durability of adhesive film joints is of significance to industrial process.
机译:目的-本文的目的是研究胶粘剂-聚对苯二甲酸乙二醇酯薄膜接头的耐久性。设计/方法/方法-粘合剂-聚对苯二甲酸乙二醇酯接缝是用聚对苯二甲酸乙二醇酯薄膜制备的,该薄膜是由巯基乙酸,萜烯烃树脂和丙酮在室温下分解而合成的。这些接缝的特点是通过剥离强度测试,能量色散X射线光谱(EDX)和分析玻璃化转变温度(Tg)的方法来检验其耐久性。条件会引起类似的变化,即在45°C下分别具有200,300、500和600 h的时间-温度等效值,分别与在55℃下分别具有100,200、300和400 h和在65°C下的50,100,150相等。和200小时。粘合剂-聚对苯二甲酸乙二酯薄膜接头的EDX光谱变化表明,粘合剂中的水渗透速率比聚对苯二甲酸乙二酯薄膜中的水渗透速率快。在湿度老化过程中,用Co〜(60)辐照处理的胶粘剂-聚对苯二甲酸乙二酯薄膜接头的剥离强度下降率要低于用丙酮洗涤或化学处理的胶粘剂-原始值/纸EDX用于分析胶膜接头的耐久性对工业过程具有重要意义。

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