We report new developments on the chemical vapor deposition growth of 0.4 am single-walled carbon nanotubes (SWCNTs) inside the linear channels of the aluminophosphate zeolite, AlPO4-5 (AFI), single crystals (0.4 nm-SWCNT@AFI). Ethylene (C2H4) and carbon monoxide (CO) were used as the feedstock. Polarized Raman spectroscopy was used to analyze the structure and quality of SWCNTs, both the radial breathing mode and G-band are much clearer and stronger than the samples grown by the old process which used template tripropylamine molecules for growing SWCNT@AFI. From the Raman spectra, it is clearly seen that the RBM is composed of two peaks at 535 and 551 cm~(-1). By using the pseudopo-tential module in Material Studio to calculate the Raman lines, the 535 cm~(-1) peak is attributed to the (5,0) SWCNTs and the 551 cm~(-1) peak to the (3,3) SWCNTs. The abundance of (4,2) is relatively small. Thermal gravity analysis showed that while the samples grown by CO display less than 1 wt% of carbon, for the samples heated in C2H4 atmosphere the weight percentage of SWCNTs is around 10%, which implies ~30% of the AFI channels are occupied with SWCNTs, a significant increase compared with the previous samples.
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