A study of active sites for alkene and alkane oxidation over Mo and V mixed oxide catalysts using ~(18)O tracer and Raman spectroscopy

Takehiko Ono; Nobuaki Ogata; Hideo Numata

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A study of active sites for alkene and alkane oxidation over Mo and V mixed oxide catalysts using ~(18)O tracer and Raman spectroscopy

机译：使用〜（18）O示踪剂和拉曼光谱研究Mo和V混合氧化物催化剂上烯烃和烷烃氧化的活性位点

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摘要

The oxygen ions of MoO_3, V_2O_5, #beta#-VOPO_4, #alpha#-Mg_2V_2O_7, #beta#-CoMoO_4 and #alpha#-Bi_2Mo_3O_(12) were exchanged with ~(18)O via a reduction-oxidation method and the catalytic oxidation of alkene or alkane using ~(18)O_2.

机译：通过还原氧化法将MoO_3，V_2O_5，＃beta＃-VOPO_4，＃alpha＃-Mg_2V_2O_7，＃beta＃-CoMoO_4和＃alpha＃-Bi_2Mo_3O_（12）的氧离子与〜（18）O交换，〜（18）O_2催化烯烃或烷烃的氧化。

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来源
《Topics in Catalysis》 |2001年第4期|共6页
作者
Takehiko Ono; Nobuaki Ogata; Hideo Numata;
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正文语种 eng
中图分类化学动力学、催化作用;催化反应过程;
关键词
shifts of raman bands; ~(18)o tracer; oxidative dehydrogenation; v mixed oxides; mo mixed oxides;

机译：拉曼谱带位移;〜（18）o示踪剂;氧化脱氢;v混合氧化物;mo混合氧化物;

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1. A study of active sites for alkene and alkane oxidation over Mo and V mixed oxide catalysts using ~(18)O tracer and Raman spectroscopy [J] . Takehiko Ono, Nobuaki Ogata, Hideo Numata Topics in Catalysis . 2001,第2a4期

机译：使用〜（18）O示踪剂和拉曼光谱研究Mo和V混合氧化物催化剂上烯烃和烷烃氧化的活性位点
2. Probing the Structural Changes and Redox Behavior of Mixed Molybdate Catalysts under Ammoxidation Conditions: An Operando Raman Spectroscopy Study [J] . ChemCatChem . 2016,第5期

机译：散氧化条件下混合钼酸盐催化剂的结构变化和氧化还原行为：杂散拉曼光谱研究
3. Study of active sites and mechanism responsible for highly selective CO oxidation in H_2 rich atmospheres on a mixed Cu and Ce oxide catalyst [J] . Polster C.S., Nair H., Baertsch C.D. Journal of Catalysis . 2009,第2期

机译：Cu和Ce混合氧化物催化剂上富H_2的气氛中高选择性CO氧化的活性位点和机理研究
4. PARTIAL OXIDATION OF METHANE BY MOLECULAR OXYGEN OVER SUPPORTED V_2O_5 CATALYSTS: A CATALYTIC AND in situ RAMAN SPECTROSCOPY STUDY [C] . Qun Sun, Jih-Mirn Jehng, Hangchun Hu, American Chemical Society Symposium on Methane and Alkane Conversion Chemistry . 1995

机译：通过将分子氧的分子氧掺入甲烷的部分氧化V_2O_5催化剂：催化和原位拉曼光谱研究
5. A study to determine the active site in the oxidative dehydrogenation of ethanol over mixed iron molybdate catalysts. [D] . Bates, Shane A. 2010

机译：确定在混合钼酸铁催化剂上乙醇氧化脱氢中活性位点的研究。
6. Mn (Br8TPPS) Supported on Amberlite IRA-400 as a Robust and Efficient Catalyst for Alkene Epoxidation and Alkane Hydroxylation [O] . S. Tangestaninejad, M. H. Habibi, V. Mirkhani, 2002

机译：Mn（Br8TPPS）负载在Amberlite IRA-400上作为鲁棒高效的烯烃环氧化和烷烃羟基化催化剂
7. In Situ Raman Spectroscopy of Supported Chromium Oxide Catalysts: ^18 O2- ^16 O2 Isotopic Labeling Studies [O] . Weckhuysen B.M., Wachs I.E. 1996

机译：负载型氧化铬催化剂的原位拉曼光谱：^ 18 O2- ^ 16 O2同位素标记研究
8. Isotope Studies of Fe-18Cr-3Mo (100) Oxidation Using Raman Spectroscopy [R] . Hamilton, J. C., Anderson, R. J. 1985

机译：用拉曼光谱研究Fe-18Cr-3mo（100）氧化的同位素研究

A study of active sites for alkene and alkane oxidation over Mo and V mixed oxide catalysts using ~(18)O tracer and Raman spectroscopy

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