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THE DISSOLUTION OF GALENA IN HYDROCHLORIC ACID - CHLORATE SOLUTIONS

机译:加仑在盐酸-氯酸盐溶液中的溶解

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The kinetics and mechanism of the leaching of galena in hydrocholoric acid - chlorate solutions were studied in the temperature range 40 to 70 deg C. Some physico-chemical factors that affect the leaching reaction have been investigated. The rate of leaching of lead was directly related to the temperature and concentration of the leachant, and inversely proportional to the average initial size of the particle. The non-dependence of the rate on stirring speed, the linear relationship between 1-(1-a)~(1/3) and reaction time, and the high activation energy are indicative of a surface chemically-controlled mechanism.
机译:研究了方铅矿在氢氯酸-氯酸盐溶液中在40到70摄氏度的温度下浸出的动力学和机理。研究了一些影响浸出反应的理化因素。铅的浸出速率与浸出剂的温度和浓度直接相关,与颗粒的平均初始尺寸成反比。速率与搅拌速度的不相关性,1-(1-a)〜(1/3)与反应时间之间的线性关系以及高活化能表明表面化学控制机理。

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