Novel Coupling Agents for Silica-filled Rubbers with Superior Processing Safety and Improved Hysteresis of the Vulcanizates

摘要

One challenge facing green tire technology is to achieve good silica hydrophobation/dispersion within the polymer matrix without a detrimental increase in the rubber compound's viscosity during compounding. This phenomenon is well known to be induced by premature and unwanted coupling and/or crosslinking of the traditional coupling agents. The current state-of-the-art polysulfides silanes, bis(3-triethoxysilylpropyl)tetrasulfide and to a lesser extent bis(3-triethoxysilylpropyl)disulfide ("Product Application--VP Si 75/VP X 75-S in the Rubber Industry," Degussa Huls Report No. PA 723. IE), need to be carefully incorporated with careful temperature control during the rubber compounding to prevent this "scorchy" behavior. This paper will present novel monofunctional silanes which are suited for preparing highly silica-loaded rubber compounds of superior processability, while applying fewer mixing passes, thereby reducing mixing times which can lead to improved productivity and cost savings. Additionally, these safer coupling agents can be processed at higher temperatures which can, again, lead to reduced mixing time and better ethanol removal thereby improving the tire's physical properties and reducing the volatile organic compounds generated during the tire's use. The rubber compounds produced using these monofunctional silanes are characterized by lower Mooney viscosity and improved processability. Advantageously, within these novel chemical classes of coupling agents, selective functionalization of the silanes allows production of tailor-made coupling agents which can respond to the specific requirements of the tire industry (Vilgis, T A. and Heinrich, G., "Die Physic des Autoreifens," Physikalische Blatter, Vol. 57, 2001, pp. 1-7).