Preparation of a Stable Trifluoroborate Salt for the Synthesis of 1-Aryl-2,2-difluoro-enolethers and/or2,2-Difluoro-1-aryl-ketones via Palladium-Mediated Cross-Coupling

Jason D. Katz; Blair T. Lapointe; Christopher J. Dinsmore

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Preparation of a Stable Trifluoroborate Salt for the Synthesis of 1-Aryl-2,2-difluoro-enolethers and/or2,2-Difluoro-1-aryl-ketones via Palladium-Mediated Cross-Coupling

机译：稳定的三氟硼酸盐的制备，用于通过钯介导的交叉偶联合成1-芳基-2,2-二氟-烯醇醚和/或2,2-二氟-1-芳基酮

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A bench-stable potassium trifluoroborate enol ether re-agent has been prepared. This reagent is suitable for theincorporation of 2,2-difluoroenolethers into aryl andheteroaryl systems via palladium-mediated cross-cou-pling 'with suitable halide coupling partners.

机译：制备了稳定的三氟硼酸钾烯醇醚试剂。该试剂适合于通过钯与合适的卤化物偶合伴侣通过交联交联将2，2-二氟乙烯醚掺入芳基和杂芳基体系中。

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《The Journal of Organic Chemistry》 |2009年第22期|共4页
作者
Jason D. Katz; Blair T. Lapointe; Christopher J. Dinsmore;
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正文语种 eng
中图分类有机化学;
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Preparation; Synthesis; partners;

机译：制备;合成;伙伴;

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1. Preparation of a Stable Trifluoroborate Salt for the Synthesis of 1-Aryl-2,2-difluoro-enolethers and/or2,2-Difluoro-1-aryl-ketones via Palladium-Mediated Cross-Coupling [J] . Jason D. Katz, Blair T. Lapointe, Christopher J. Dinsmore The Journal of Organic Chemistry . 2009,第22期

机译：稳定的三氟硼酸盐的制备，用于通过钯介导的交叉偶联合成1-芳基-2,2-二氟-烯醇醚和/或2,2-二氟-1-芳基酮
2. Improved method for the conversion of pinacolboronic esters into trifluoroborate salts: facile synthesis of chiral secondary and tertiary trifluoroborates [J] . Bagutski V, Ros A, Aggarwal VK Tetrahedron . 2009,第48期

机译：频哪醇硼酸酯转化为三氟硼酸盐的改进方法：手性仲和叔三氟硼酸盐的简便合成
3. Improved method for the conversion of pinacolboronic esters into trifluoroborate salts: facile synthesis of chiral secondary and tertiary trifluoroborates [J] . Bagutski V, Ros A, Aggarwal VK Tetrahedron . 2009,第48期

机译：频哪醇硼酸酯转化为三氟硼酸盐的改进方法：手性仲和叔三氟硼酸盐的简便合成
4. Synthesis of Onium-ferrate Salts and Their Application to the Cross-coupling of Alkyl Halides with Aryl Grignard Reagents [C] . Tsubasa Maruyama, Toru Hashimoto, Yoshitaka Yamaguchi 日本化学会春季年会講演予稿集 . 2018

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6. Synthesis of 9-arylalkynyl- and 9-aryl-substituted benzobquinolizinium derivatives by Palladium-mediated cross-coupling reactions [O] . Siva Sankar Murthy Bandaru, Darinka Dzubiel, Heiko Ihmels, 2018

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8. Polynitrogen Chemistry, Synthesis, Characterization, and Crystal Structure of Surprisingly Stable Fluoroantimonate Salts of N5(+). [R] . Vij, A., Wilson, W. W., Vij, V., 2001

机译：N5（+）的令人惊讶的稳定的氟锑酸盐的多氮化学，合成，表征和晶体结构。

Preparation of a Stable Trifluoroborate Salt for the Synthesis of 1-Aryl-2,2-difluoro-enolethers and/or2,2-Difluoro-1-aryl-ketones via Palladium-Mediated Cross-Coupling

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