Kinetics study for photodegradation of methylene blue dye by titanium dioxide powder prepared by selective leaching method

摘要

The kinetics of photodegradation of methylene blue (MB) dye by titanium dioxide (TiO _2) powder were investigated using elementary reactions. TiO _2 powders were prepared by a selective leaching method consisted of processes of CaHPO _4 precipitation, heat treatment, and acid leaching to obtain high crystalline anatase. The obtained TiO _2 samples had wide ranges of specific surface areas (523 m ~2/g) and densities of Ti ~3 defects (90480×10 ~(12)spin/g) without a significant change in the anatase phase ratio ranging 0.860.91 in mass ratio. The MB photodegradation rate was expressed as functions of specific surface area and density of Ti ~3 defects under the experimental condition that the photodegradation rate was proportional to UV irradiation intensity and the adsorbed MB amount was proportional to specific surface area. A proposed equation for calculation of photodegradation ate demonstrated greater effect of specific surface area than density of Ti ~3 defects for MB photodegradation.