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Adsorption of polydisperse polymer chains

机译:多分散聚合物链的吸附

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摘要

The adsorption of polydisperse ideal polymer chains is shown to be sensitive to the large N tail of the distribution of chains. If and only if the number of chains decays more slowly than exponentially is there an adsorption transition like that of monodisperse infinite chains. If the number decays exponentially the adsorption density diverges continuously at a temperature which is a function of the mean chain length. At low coverages, chains with repulsive monomer-monomer interactions show the same qualitative behavior.
机译:已显示多分散理想聚合物链的吸附对链分布的大N尾敏感。当且仅当链数的衰减比指数衰减的慢时,才出现像单分散无限链的吸附跃迁。如果数量呈指数下降,则吸附密度在作为平均链长的函数的温度下会连续发散。在低覆盖率下,具有排斥性单体-单体相互作用的链显示出相同的定性行为。

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