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Target and trapping problems: From the ballistic to the diffusive regime

机译:目标和诱捕问题:从弹道到扩散体制

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The target and trapping problems refer to the reaction A + B -> B. In the target problem a single A particle is fixed in space and surrounded by B's allowed to move freely, while in the trapping problem the B's are fixed and the A is able to move. Exact solutions are found for both problems in the ballistic regime, in all dimensions. We show that the solution of the target problem provides a mean-field approximation to the solution of the trapping problem, not only in the diffusive regime, but also for arbitrary noise. This approximate solution works well in the diffusive regime, but not when motion is ballistic, since it breaks down at very early times. We show that the time-dependent rate coefficients in both the target and trapping problems remain finite at t = 0 for arbitrarily strong noise intensities. This behavior is in contrast to the diffusion theory prediction that the coefficient diverges at t = 0. A recently developed model that discretizes the velocity, allowing only three values, +- v and 0, is used to study the reaction kinetics of both the trapping and target problems in one dimension over the entire range of noise intensities. The solutions are used to study the effect of noise intensity on the mean survival time. We show that in the target problem this time decreases monotonically with increasing noise, while in the trapping problem this time exhibits a turnover behavior. We argue that a similar turnover occurs in the one-dimensional trapping problem when particle motion is governed by a Langevin equation.
机译:目标和捕获问题是指反应A + B->B。在目标问题中,单个A粒子固定在空间中并被B允许自由移动,而在捕获问题中,B固定并且A是能够移动。在弹道方面的所有问题上都找到了精确的解决方案。我们表明,目标问题的解决方案提供了均值场逼近,不仅针对扩散问题,而且针对任意噪声,均对捕获问题的解决方案提供了解决方案。这种近似解在扩散状态下效果很好,但是在运动是弹道运动时效果不佳,因为它在很早的时候就崩溃了。我们表明,对于任意强噪声强度,目标问题和捕获问题中随时间变化的速率系数在t = 0时都保持有限。此行为与扩散理论预测相反,扩散理论预测系数在t = 0时发散。最近开发的离散速度模型,仅允许三个值+-v和0用于研究两种捕集的反应动力学。并在整个噪声强度范围内一维解决问题。该解决方案用于研究噪声强度对平均生存时间的影响。我们表明,在目标问题中,这次随着噪声的增加而单调减少,而在捕获问题中,这次表现出翻转行为。我们认为,当粒子运动受Langevin方程控制时,一维陷波问题也会发生类似的转换。

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