首页> 外文期刊>THE CANADIAN MINERALOGIST >ZIRCONOLITE AND Zr-Th-U MINERALS IN CHROMITITES OF THE FINERO COMPLEX, WESTERN ALPS, ITALY: EVIDENCE FOR CARBONATITE-TYPE METASOMATISM IN A SUBCONTINENTAL MANTLE PLUME
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ZIRCONOLITE AND Zr-Th-U MINERALS IN CHROMITITES OF THE FINERO COMPLEX, WESTERN ALPS, ITALY: EVIDENCE FOR CARBONATITE-TYPE METASOMATISM IN A SUBCONTINENTAL MANTLE PLUME

机译:意大利西阿尔卑斯山FINERO COMPLEX铬铁矿中的锆石和Zr-Th-U矿物:次大陆幔柱中碳酸盐型介晶作用的证据

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Zirconolite (CaZrTi_2O_7) associated with baddeleyite (ZrO_2), thorianite (ThO_2), uraninite (U02), thorite or huttonite (ThSiO_4) annd zircon (ZrSiO_4) has been discovered in chromitites of the Finero mantle-derived massif, in the Western Alps of Italy. The "exotic" minerals do not occur in late veins or fractures; they are part of the accessory assemblage (phlogopite, amphibole, apatite, ilmenite, geikielite, rutile, molybdenite, and Mg-Ca carbonates) formed as a result of metasomatism of the Finero mantle. Textural relations of zirconolite and the Zr-Th-U minerals indicate crystallization with the chromite-olivine-orthopyroxene assemblage between 800 deg and ~600 deg C, at a given pressure of 1.0 GPa. Zirconolite is an indicator of silica-undersaturated conditions. Its composition, characterized by the prevalence of Th and U over Nb and Ta, is similar to that of zirconolite from some carbonatite complexes. The close association with Zr-Th-U minerals, and with the carbonatite-compatible elements Y, Hf, Pb, and LREE, is symptomatic of the carbonatitic character of metasomatism at Finero. The formation of a carbonatite-type liquid and related hydrous fluid is commonly related to the emplacement of mantle plumes in continental rift systems worldwide. This supports the inference that the metasomatism of the Finero mantle was a result of mantle diapirism at the base of the continental crust induced by extensional tectonics in pre-Hercynian times.
机译:在西部地区Finero地幔衍生的地块的铬铁矿中发现了锆石沸石(CaZrTi_2O_7)与坏方铅矿(ZrO_2),闪锌矿(ThO_2),尿石(U02),菱铁矿或水辉石(ThSiO_4)和锆石(ZrSiO_4)。意大利。 “外来”矿物不会出现在后期的静脉或骨折中。它们是由于Finero地幔交代作用而形成的辅助组合(金云母,角闪石,磷灰石,钛铁矿,geikielite,金红石,辉钼矿和Mg-Ca碳酸盐)的一部分。锆石和Zr-Th-U矿物的织构关系表明,在给定的1.0 GPa压力下,铬铁矿-橄榄石-邻苯二茂合物在800摄氏度至〜600摄氏度之间结晶。锆石沸石是二氧化硅不饱和条件的指示。其成分的特征是Th和U高于Nb和Ta,与某些碳酸盐复合物中的锆石相似。与Zr-Th-U矿物以及与碳酸盐兼容的元素Y,Hf,Pb和LREE的密切联系是Finero交代作用的碳酸盐特征的征兆。碳酸盐型液体和相关含水流体的形成通常与地幔柱在全球大陆裂谷系统中的位置有关。这支持了Finero地幔的交代作用是Hercynian以前的扩张构造引起的地壳底裂作用的推论的推论。

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