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首页> 外文期刊>The Canadian Journal of Chemical Engineering >Drag reduction in Turbulent Pipeline Flow of Mixed Nonionic polymer and Cationic Surfactant Systems
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Drag reduction in Turbulent Pipeline Flow of Mixed Nonionic polymer and Cationic Surfactant Systems

机译:混合非离子聚合物和阳离子表面活性剂体系湍流管道流动的减阻

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摘要

Turbulent drag reduction behaviour of a mixed nonionic polymer/cationic surfactant system was studied in a pipeline flow loop to explore the synergistic effects of polymeric and surfactant drag reducing additives. The nonionic polymer used was polyethylene oxide (PEO) at three different concentrations (500, 1000, and 2000 ppm). The surfactant used was cationic octadecyltrimethylammonium chloride (OTAC) at concentration levels of 1000 and 2500 ppm. Sodium salicylate (NaSal) was used as a counter-ion for the surfactant at a molar ratio of 2 (MR = Salt/OTAC = 2). Relative viscosity and surface tension were measured for different combinations of PEO and OTAC. While the relative viscosities demonstrated a week interaction between the polymer and the surfactant, the surface tension measurements exhibited negligible interaction. The pipeline results show a considerable synergistic effect, that is, the mixed polymer-surfactant system gives a significantly higher drag reduction (lower friction factors) as compared with pure polymer or pure surfactant. The addition of surfactant to the polymer always enhances drag reduction. However, the synergistic effect in mixed system is stronger at low polymer concentrations and high surfactant concentrations.
机译:在管道流动回路中研究了混合非离子聚合物/阳离子表面活性剂体系的湍流减阻行为,以探索聚合物和表面活性剂减阻添加剂的协同作用。使用的非离子聚合物是三种不同浓度(500、1000和2000 ppm)的聚环氧乙烷(PEO)。所用的表面活性剂是浓度为1000和2500ppm的阳离子十八烷基三甲基氯化铵(OTAC)。水杨酸钠(NaSal)用作表面活性剂的抗衡离子,摩尔比为2(MR =盐/ OTAC = 2)。测量了PEO和OTAC的不同组合的相对粘度和表面张力。尽管相对粘度表明聚合物和表面活性剂之间有一个星期的相互作用,但表面张力的测量却显示出可忽略的相互作用。管线结果显示出显着的协同作用,即,与纯聚合物或纯表面活性剂相比,混合的聚合物-表面活性剂体系具有明显更高的减阻(较低的摩擦系数)。向聚合物中添加表面活性剂总是增强减阻作用。然而,在低聚合物浓度和高表面活性剂浓度下,混合体系中的协同作用更强。

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