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Dynamic structure factor of a stiff polymer in a glassy solution

机译:玻璃状溶液中硬质聚合物的动态结构因子

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We provide a comprehensive overview of the current theoretical understanding of the dynamic structure factor of stiff polymers in semidilute solution based on the wormlike chain (WLC) model. We extend previous work by computing exact numerical coefficients and an expression for the dynamic mean square displacement (MSD) of a free polymer and compare various common approximations for the hydrodynamic interactions, which need to be treated accurately if one wants to extract quantitative estimates for model parameters from experimental data. A recent controversy about the initial slope of the dynamic structure factor is thereby resolved. To account for the interactions of the polymer with a surrounding (sticky) polymer solution, we analyze an extension of the WLC model, the glassy wormlike chain (GWLC), which predicts near power law and logarithmic long-time tails in the dynamic structure factor.
机译:我们提供了基于蠕虫链(WLC)模型的半稀溶液中硬质聚合物动力学结构因子的当前理论理解的全面概述。我们通过计算精确的数值系数和游离聚合物的动态均方位移(MSD)表达式来扩展先前的工作,并比较流体动力学相互作用的各种常见近似值,如果要提取模型的定量估计值,则需要对其进行精确处理。实验数据中的参数。从而解决了有关动态结构因子初始斜率的最新争议。为了说明聚合物与周围(粘性)聚合物溶液的相互作用,我们分析了WLC模型的延伸,即玻璃状蠕虫状链(GWLC),该模型预测了动态结构因子中的近幂定律和对数长时间尾部。

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