The role of water in the structures of synthetic hallimondite, Pb-2[(UO2)(AsO4)(2)](H2O)(n) and synthetic parsonsite, Pb-2[(UO2)(PO4)(2)](H2O)(n), 0 <= n <= 0.5

摘要

The crystal structures of synthetic hallimondite and synthetic parsonsite have been refined by full-matrix least-squares techniques to agreement indices (hallimondite, parsonsite) wR(2) of 5.5, and 7.6% for all data, and R1 of 2.7 and 3.4%, calculated for 3391 and 3181 unique observed reflections (F-o greater than or equal to 4sigma(F)), respectively. Hallimondite is triclinic, space group P (1) over bar, Z = 2, a = 7.1153(8), b = 10.4780(12), c = 6.8571(8) Angstrom, alpha = 101.178(3)degrees, beta = 95.711(3)degrees, gamma = 86.651(3)degrees, V = 498.64(3) Angstrom(3), and is isostructural with parsonsite, triclinic, space group P (1) over bar, Z = 2, a = 6.8432(5), b = 10.4105(7), c = 6.6718(4) Angstrom, alpha = 101.418(1)degrees, beta = 98.347(2)degrees, gamma = 86.264(2)degrees, V = 460.64(5) Angstrom(3). In both structures, hexavalent uranium occurs as a uranyl pentagonal bipyramid. The uranyl polyhedra share an edge, forming dimers that are linked by edge- and vertex-sharing with arsenate or phosphate tetrahedra to form chains along [001]. Two symmetrically distinct Pb positions connect the chains. In hallimondite, a partially occupied oxygen atom is located in the cavity between the uranyl arsenate chains and Pb positions, and is attributed to an H2O group. The crystal of synthetic parsonsite investigated does not have appreciable electron density at this position, but its structural cavity is large enough to contain H2O. The presence of H2O in synthetic hallimondite, and its absence in synthetic parsonsite, are supported by the results of FTIR spectroscopy. In conjunction with thermogravimetric results from the literature, we suggest that the formula of parsonsite should be considered Pb-2[(UO2)(PO4)(2)](H2O)(n) and hallimondite, Pb-2[(UO2)(ASO(4))(2)](H2O)(n) with 0 less than or equal to n less than or equal to 0.5 in each case.