NOVEL ROUTE TO THE SYNTHESIS OF HYDROXYLATED PIPERIDINE AND PYRROLIDINE DERIVATIVES VIA THE INTRAMOLECULAR REACTION OF GAMMA-AMINOALLYLSTANNANE WITH ALDEHYDE

Kadota I.; Saya S.; Yamamoto Y.; Kawada M.

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >NOVEL ROUTE TO THE SYNTHESIS OF HYDROXYLATED PIPERIDINE AND PYRROLIDINE DERIVATIVES VIA THE INTRAMOLECULAR REACTION OF GAMMA-AMINOALLYLSTANNANE WITH ALDEHYDE

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NOVEL ROUTE TO THE SYNTHESIS OF HYDROXYLATED PIPERIDINE AND PYRROLIDINE DERIVATIVES VIA THE INTRAMOLECULAR REACTION OF GAMMA-AMINOALLYLSTANNANE WITH ALDEHYDE

机译：γ-酰胺基丙烯酰胺与醛的分子内反应合成羟基哌啶子碱和吡咯烷衍生物的新路线

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The Lewis acid mediated intramolecular reaction of gamma-aminoallylstannane 6 gave trans-beta-hydroxypiperidine derivative 7a as a major product. On the other hand, the thermal cyclization of 6 and 8 afforded cis-beta hydroxypiperidine 7b and pyrrolidine derivative 9b, respectively, with very high stereoselectivity. [References: 12]

机译：路易斯酸介导的γ-氨基烯丙基锡烷6的分子内反应得到反式β-羟基哌啶衍生物7a作为主要产物。另一方面，对6和8的热环化分别提供具有非常高的立体选择性的顺式-β羟基哌啶7b和吡咯烷衍生物9b。 [参考：12]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1996年第12期|共4页
作者
Kadota I.; Saya S.; Yamamoto Y.; Kawada M.;
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正文语种 eng
中图分类有机化学;
关键词
Ring-system; Ethers;

机译：环系统;醚;

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专利

1. 反应型受阻胺4-丙烯酰胺基-2,2,6,6-四甲基哌啶(AATP)熔融本体光聚合反应动力学研究 [J] . 刘晓暄, 邓湘华, 郭旭, 浙江大学学报：A卷英文版 . 2004,第004期
2. NOVEL ROUTE TO THE SYNTHESIS OF HYDROXYLATED PIPERIDINE AND PYRROLIDINE DERIVATIVES VIA THE INTRAMOLECULAR REACTION OF GAMMA-AMINOALLYLSTANNANE WITH ALDEHYDE [J] . Kadota I., Saya S., Yamamoto Y., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1996,第12期

机译：γ-酰胺基丙烯酰胺与醛的分子内反应合成羟基哌啶子碱和吡咯烷衍生物的新路线
3. Microwave‐assisted One‐pot, Three‐component Regiospecific and Sterospecific Synthesis of Spiro Indanone Pyrrolidine/Piperidine Fused Nitrochromene Derivatives Through 1,3‐Dipolar Cycloaddition Reactions [J] . Nayak Sabita, Panda Pravati, Mohapatra Seetaram, Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2019,第6期

机译：微波辅助单锅，三组分细胞纤维素吡咯烷/哌啶熔融硝基溴代烯衍生物通过1,3-二极管环加成反应
4. Sequential Biocatalytic Aldol Reactions in Multistep Asymmetric Synthesis: Pipecolic Acid, Piperidine and Pyrrolidine (Homo)Iminocyclitol Derivatives from Achiral Building Blocks [J] . Anna Soler, Xavier Garrabou, Karel Hernandez Advanced synthesis & catalysis . 2014,第14a15期

机译：多步不对称合成中的顺序生物催化醛醇缩合反应：非手性结构单元中的胡椒酸，哌啶和吡咯烷（均）亚氨基环醇衍生物
5. Highly Efficient Synthesis of Oxindole Derivatives via Catalytic Intramolecular C-H Insertion Reactions of Diazoamides [C] . Nga Phan-Thi-Thanh, Masaya Tone, Hayato lnoue International Conference on Science and Technology . 2020

机译：通过催化分子内C-H插入式重氮酰胺的催化分子内C-H插入反应高效合成氧吲哚衍生物
6. Synthesis of functionalized pyrrolidines, piperidines and spirocyclic nitrogen heterocycles via a novel variation of the Heck reaction. [D] . Herr, R. Jason. 1994

机译：通过Heck反应的新变化合成功能化的吡咯烷，哌啶和螺环氮杂环。
7. Intramolecular thermal reactions of the derivatives of 5′-azido-5′-deoxyuridine. A new feasible route to the regio- and stereospecific synthesis of reversed nucleosides carrying a substituted five-membered heterocycle [O] . Tadashi Sasaki, Katsumaro Minamoto, Toshimichi Suzuki, 1978

机译：5-叠氮基-5-脱氧尿苷衍生物的分子内热反应。带有取代的五元杂环的反向核苷的区域和立体特异性合成的新可行途径
8. Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes [O] . Ohmiya, Hirohisa, Yoshida, Mika, Sawamura, Masaya 2010

机译：通过Cu（I）催化的烯烃分子内加氢胺化反应生成羟基化吡咯烷和哌啶衍生物的无保护基团

NOVEL ROUTE TO THE SYNTHESIS OF HYDROXYLATED PIPERIDINE AND PYRROLIDINE DERIVATIVES VIA THE INTRAMOLECULAR REACTION OF GAMMA-AMINOALLYLSTANNANE WITH ALDEHYDE

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