A NOVEL PHOSPHITYLATING REAGENT FOR IN SITU GENERATION OF DEOXYRIBONUCLEOSIDE PHOSPHORAMIDITES

Zhang ZD.; Tang JY.

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A NOVEL PHOSPHITYLATING REAGENT FOR IN SITU GENERATION OF DEOXYRIBONUCLEOSIDE PHOSPHORAMIDITES

机译：原位生成脱氧核糖核苷磷酸酯的新型磷酸化试剂

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摘要

A new phosphitylating reagent, 2-cyanoethoxy(N,N-diisopropylamino)3-n triazolylphosphine (1), has been prepared and effectively used in in situ generation of 5'-DMT-nucleoside phosphoramidites and automated syntheses of oligonucleotides. [References: 12]

机译：一种新的磷酸化试剂2-氰基乙氧基（N，N-二异丙氨基氨基）3-n三唑基膦（1）已制备出来，并有效地用于5'-DMT-核苷亚磷酰胺的原位生成和寡核苷酸的自动合成。 [参考：12]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1996年第3期|共4页
作者
Zhang ZD.; Tang JY.;
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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Oligonucleotides; Insitu; Activation; Dna;

机译：寡核苷酸;原位;活化;Dna;

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专利

1. A NOVEL PHOSPHITYLATING REAGENT FOR IN SITU GENERATION OF DEOXYRIBONUCLEOSIDE PHOSPHORAMIDITES [J] . Zhang ZD., Tang JY. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1996,第3期

机译：原位生成脱氧核糖核苷磷酸酯的新型磷酸化试剂
2. Application of 2-cyanoethyl N,N,N′,N′-tetraisopropylphosphorodiamidite for in situ preparation of deoxyribonucleoside phosphoramidites and their use in polymer-supported synthesis of oligodeoxyribonucleotides [J] . Jacques H. van Boom, John E. Marugg, John Nielsen, Nucleic acids research . 1986,第18期

机译：2-氰基乙基N，N，N'，N'-四异丙基亚磷酰胺在原位制备脱氧核糖核苷亚磷酰胺的应用及其在聚合物支持的寡聚脱氧核糖核苷酸合成中的应用
3. Analysis of hydrate exploitation by a new in-situ heat generation method with chemical reagents based on heat utilization [J] . Journal of Cleaner Production . 2020,第Mara10期

机译：基于热利用的化学试剂原位生热新方法分析水合物
4. Tropos Benzophenone-like Phosphoramidite Ligands: Highly Enantioselective Catalyses of Conjugate Addition to Nitroalkenes irrespective of the Reagents and Substrates [C] . Kazuki Wakabayashi, Kohsuke Aikawa, Koichi Mikami Symposium on Organometallic Chemistry . 2007

机译：Tropos二苯酮样磷酰亚胺配体：无论试剂和衬底如何，硝基烯烃的缀合物的高度映射性催化剂
5. I. Catalytic asymmetric addition of organozinc reagents to ketones. II. Novel 1-alkenyl-1,1-bimetallic reagents: Generation and synthetic applications [D] . Li, Hongmei 2007

机译：I.有机锌试剂向酮的催化不对称加成。二。新型1-烯基-1,1-双金属试剂：生成和合成应用
6. Application of 2-cyanoethyl NNNN-tetraisopropylphosphorodiamidite for in situ preparation of deoxyribonucleoside phosphoramidites and their use in polymer-supported synthesis of oligodeoxyribonucleotides. [O] . J Nielsen, M Taagaard, J E Marugg, 1986

机译：2-氰基乙基NNNN-四异丙基亚磷酰胺在原位制备脱氧核糖核苷亚磷酰胺的应用及其在聚合物支持的寡聚脱氧核糖核苷酸合成中的应用。
7. Application of 2-cyanoethyl N,N,N',N'-tetraisopropylphosphorodiamidite for in situ preparation of deoxyribonucleoside phosphoramidites and their use in polymer-supported synthesis of oligodeoxyribonucleotides. [O] . Nielsen, J, Taagaard, M, Marugg, J E, 1986

机译：2-氰基乙基N，N，N'，N'-四异丙基亚磷酰胺在原位制备脱氧核糖核苷亚磷酰胺的应用及其在聚合物支持的寡聚脱氧核糖核苷酸合成中的应用。

A NOVEL PHOSPHITYLATING REAGENT FOR IN SITU GENERATION OF DEOXYRIBONUCLEOSIDE PHOSPHORAMIDITES

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